A user of Flickr uploaded a German LEGO catalog which has all the coming LEGO Captain America: Civil War sets. They are as follows:
Super Heroes at the Airport (76051)
This includes minifigures of Scarlet Witch, Iron Man, Captain America, micro Ant-Man, War Machine, Agent 13 and a build-able Giant Man.
Hunt for Black Panther (76047)
This includes minifigures of Falcon, Black Widow and Black Panther.
Crossbones’ Dangerour Robbery (76050)
This includes minifigures of Captain America, Winter Soldier and Crossbones.
