A user of Flickr uploaded a German LEGO catalog that has all the coming LEGO Captain America: Civil War sets. They are as follows:
Super Heroes at the Airport (76051)
This includes minifigures of Scarlet Witch, Iron Man, Captain America, micro Ant-Man, War Machine, Agent 13, and a buildable Giant Man.
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Hunt for Black Panther (76047)
This includes minifigures of Falcon, Black Widow, and Black Panther.
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Crossbones’ Dangerous Robbery (76050)
This includes minifigures of Captain America, Winter Soldier, and Crossbones.
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